• 文献标题:   Fabrication of shape-stable composite phase change materials based on lauric acid and graphene/graphene oxide complex aerogels for enhancement of thermal energy storage and electrical conduction
  • 文献类型:   Article
  • 作  者:   LIANG K, SHI L, ZHANG JY, CHENG J, WANG XD
  • 作者关键词:   graphene/graphene oxide complex aerogel, phase change material, shape stabilization, crystallization kinetic, thermal energy storage, electrical conductivity
  • 出版物名称:   THERMOCHIMICA ACTA
  • ISSN:   0040-6031 EI 1872-762X
  • 通讯作者地址:   Beijing Univ Chem Technol
  • 被引频次:   11
  • DOI:   10.1016/j.tca.2018.04.002
  • 出版年:   2018

▎ 摘  要

This paper reported the fabrication and performance of shape-stable composite phase change materials (PCMs) based on lauric acid (LA) and graphene/graphene oxide (GO) complex aerogels for enhancement of thermal energy storage and electrical conduction. The graphene/GO complex aerogels were prepared through a reduction reaction and freeze-drying technology, and then LA was incorporated into the complex aerogels via vacuum-assisted impregnation. The complex aerogels and their composites were characterized by scanning electron microscopy, X-ray powder diffraction and Fourier-transform infrared spectroscopy. These LA/complex aerogel composites not only exhibited high electrical conductivity but also achieved high phase-change enthalpies more than 198.1/g, high heat-charging and discharging efficiency more than 90%, excellent cyclic stability, good phase-change reversibility and good shape stability. The crystallization kinetic study demonstrated that the aerogel framework could generate a heterogeneous nucleation effect on the crystallization of LA and therefore improved the crystallization rate of LA under both nonisothermal and isothermal conditions.