• 文献标题:   Determination of the antioxidant propyl gallate in meat by using a screen-printed electrode modified with CoSe2 nanoparticles and reduced graphene oxide
  • 文献类型:   Article
  • 作  者:   CHEN SM, MANAVALAN S, RAJAJI U, GOVINDASAMY M, CHEN TW, ALI MA, ALNAKHLI AK, ALHEMAID FMA, ELSHIKH MS
  • 作者关键词:   antioxidant, electrochemical sensor, reduced graphene oxide, dichalcogenide, food additive
  • 出版物名称:   MICROCHIMICA ACTA
  • ISSN:   0026-3672 EI 1436-5073
  • 通讯作者地址:   King Saud Univ
  • 被引频次:   7
  • DOI:   10.1007/s00604-018-3048-3
  • 出版年:   2018

▎ 摘  要

A voltammetric sensor is described for the quantitation of propyl gallate (PG). A screen-printed carbon electrode (SPCE) was modified with reduced graphene sheets that were decorated with cobalt diselenide nanoparticles (CoSe2@ rGO). The material was hydrothermally prepared and characterized by several spectroscopic techniques. The modified SPCE displays excellent electrocatalytic ability towards PG. Differential pulse voltammetry, with a peak voltage at 0.34 V (vs. Ag/ AgCl) has a sensitivity of 12.84 mu A center dot mu M-1 center dot cm-2 and a detection limit as low as 16 nM. The method is reproducible, selective, and practical. This method was applied to the determination of PG in spiked meat samples, and the result showed an adequate recovery.