• 文献标题:   Do-It-Yourself Transfer of Large-Area Graphene Using an Office Laminator and Water
  • 文献类型:   Article
  • 作  者:   SHIVAYOGIMATH A, WHELAN PR, MACKENZIE DMA, LUO BR, HUANG DP, LUO D, WANG MH, GAMMELGAARD L, SHI HF, RUOFF RS, BOGGILD P, BOOTH TJ
  • 作者关键词:  
  • 出版物名称:   CHEMISTRY OF MATERIALS
  • ISSN:   0897-4756 EI 1520-5002
  • 通讯作者地址:   Tech Univ Denmark
  • 被引频次:   19
  • DOI:   10.1021/acs.chemmater.8b04196
  • 出版年:   2019

▎ 摘  要

We demonstrate a simple method for transferring large areas (up to A4-size sheets) of CVD graphene from copper foils onto a target substrate using a commercially available polyvinyl alcohol polymer foil as a carrier substrate and commercial hot-roll office laminator. Through the use of terahertz time-domain spectroscopy and Raman spectroscopy, large-area quantitative optical contrast mapping, and the fabrication and electrical characterization of similar to 50 individual centimeter-scale van der Pauw field effect devices, we show a nondestructive technique to transfer large-area graphene with low residual doping that is scalable, economical, reproducible, and easy to use and that results in less doping and transfer-induced damage than etching or electrochemical delamination transfers. We show that the copper substrate can be used multiple loss of material and no observable reduction in graphene quality. We have additionally demonstrated the transfer of multilayer hexagonal boron nitride from copper and iron foils. Finally, we note that this approach allows graphene to be supplied on stand-alone polymer supports by CVD graphene manufacturers to end users, with the only equipment and consumables required to transfer graphene onto target substrates being a commercial office laminator and water.