• 文献标题:   Intercalation structure of vanadium nitride nanoparticles growing on graphene surface toward high negative active material for supercapacitor utilization
  • 文献类型:   Article
  • 作  者:   HE TQ, WANG Z, LI XM, TAN YT, LIU Y, KONG LB, KANG L, CHEN CM, RAN F
  • 作者关键词:   vanadium nitride, go, surface polymerization, hybrid material, supercapacitor
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   Lanzhou Univ Technol
  • 被引频次:   20
  • DOI:   10.1016/j.jallcom.2018.12.149
  • 出版年:   2019

▎ 摘  要

Here, we use the method of electrochemical surface-initiated atom transfer radical polymerization to prepare VN nanoparticle/GO composites. VN nanoparticles is uniformly distributed onto the surface of GO, which forms an intercalation structure. Synergistic effect of the electrochemical active material of VN and good conductive substrate of GO significantly improves the efficiency of the electrochemically active materials to ensure the electrode behavior of charging and discharging process goes smoothly. In 2 M KOH electrolyte, the electrode material of VN/GO hybrid exhibits good specific capacitance of 109.7 F/g. And after 5000 cycles, the capacitance retention rate still reaches 93% of the initial capacity. (C) 2018 Elsevier B.V. All rights reserved.