• 文献标题:   Modification of Structural and Luminescence Properties of Graphene Quantum Dots by Gamma Irradiation and Their Application in a Photodynamic Therapy
  • 文献类型:   Article
  • 作  者:   JOVANOVIC SP, SYRGIANNIS Z, MARKOVIC ZM, BONASERA A, KEPIC DP, BUDIMIR MD, MILIVOJEVIC DD, SPASOJEVIC VD, DRAMICANIN MD, PAVLOVIC VB, MARKOVIE BMT
  • 作者关键词:   graphene quantum dot, gamma irradiation, photoluminescence, quantum yield, photodynamic therapy
  • 出版物名称:   ACS APPLIED MATERIALS INTERFACES
  • ISSN:   1944-8244
  • 通讯作者地址:   Univ Belgrade
  • 被引频次:   37
  • DOI:   10.1021/acsami.5b08226
  • 出版年:   2015

▎ 摘  要

Herein, the ability of gamma irradiation to enhance the photoluminescence properties of graphene quantum dots (GQDs) was investigated. Different doses of gamma-irradiation were used on GQDs to examine the way in which their structure and optical properties can be affected. The photoluminescence quantum yield was increased six times for the GQDs irradiated with high doses compared to the nonirradiated material. Both photoluminescence lifetime and values of optical band gap were increased with the dose of applied gamma irradiation. In addition, the exploitation of the gamma-irradiated GQDs as photosensitizers was examined by monitoring the production of singlet oxygen under UV illumination. The main outcome was that the GQDs irradiated at lower doses act as better photoproducers than the ones irradiated at higher doses. These results corroborate that the structural changes caused by gamma irradiation have a direct impact on GQD ability to produce singlet oxygen and their photostability under prolonged UV illumination. This makes low-dose irradiated GQDs promising candidates for photodynamic therapy.