• 文献标题:   Reduced Graphene Oxide-Based Foam as an Endocrine Disruptor Adsorbent in Aqueous Solutions
  • 文献类型:   Article
  • 作  者:   N DIAYE J, POORAHONG S, HMAM O, JIMENEZ GC, IZQUIERDO R, SIAJ M
  • 作者关键词:   reduced graphene oxide, membrane, endocrine disruptor, adsorption, langmuir, freundlich
  • 出版物名称:   MEMBRANES
  • ISSN:  
  • 通讯作者地址:   Univ Quebec
  • 被引频次:   0
  • DOI:   10.3390/membranes10110340
  • 出版年:   2020

▎ 摘  要

A stable and magnetic graphene oxide (GO) foam-polyethyleneimine-iron nanoparticle (GO-PEI-FeNPs) composite has been fabricated for removal of endocrine disruptors-bisphenol A, progesterone and norethisterone-from aqueous solution. The foam with porous and hierarchical structures was synthesized by reduction of graphene oxide layers coupled with co-precipitation of iron under a hydrothermal system using polyethyleneimine as a cross linker. The presence of magnetic iron nanoparticles facilitates the separation process after decontamination. The foam was fully characterized by surface and structural scanning electron microscopy, Fourier transform infrared spectroscopy, Raman spectroscopy and X-ray photoelectron spectroscopy. The foam exhibits a high adsorption capacity, and the maximum adsorption percentages are 68%, 49% and 80% for bisphenol A, progesterone and norethisterone, respectively. The adsorption process of bisphenol A is explained according to the Langmuir model, whereas the Freundlich model was used for progesterone and norethisterone adsorption.