• 文献标题:   Reduced Graphene Oxide-Based Spectrally Selective Absorber with an Extremely Low Thermal Emittance and High Solar Absorptance
  • 文献类型:   Article
  • 作  者:   LIAO QH, ZHANG PP, YAO HZ, CHENG HH, LI C, QU LT
  • 作者关键词:   graphene, solar energy conversion, solar steam escape, spectrally selective absorber
  • 出版物名称:   ADVANCED SCIENCE
  • ISSN:  
  • 通讯作者地址:   Tsinghua Univ
  • 被引频次:   1
  • DOI:   10.1002/advs.201903125 EA FEB 2020
  • 出版年:   2020

▎ 摘  要

Carbon-based black materials exhibit strong solar absorptance (alpha(solar) >0.90), which play key roles in transforming solar energy into available power for solar-thermal, thermophotovoltaic, thermoelectric, and many other systems. However, because of high thermal emittance (>95%), these carbon-based materials always cause huge energy loss that hinders the solar-thermal conversion efficiency tremendously. In this study, a reduced graphene oxide-based spectrally selective absorber (rGO-SSA) is demonstrated, which possesses a recorded low thermal emittance (approximate to 4%) and high solar absorptance (alpha(solar) approximate to 0.92) by easily regulating the reduction level of inner 2D graphene sheets. Compared to conventional carbon-based black materials, thermal emittance of this rGO-SSA is largely reduced by approximate to 95.8% and the cutoff wavelength of rGO-SSA is broadband-tunable that can range from 1.1 to 3.2 mu m. More importantly, this simply sol-gel coated rGO-SSA has high temperature tolerance at 800 degrees C for 96 h that is hardly achieved by other cermet-based or photonic-based SSAs. Based on this rGO-SSA, ultrafast solar steam escape (0.94 mg cm(-2) s(-1)) under concentrated solar irradiance is achieved directly. The insight from this study will provide a new strategy for constructing thermally stable carbon-based SSAs and greatly facilitate the solar-thermal practical significance.