• 文献标题:   Porous Silicon Skeleton as Catalysts for Hydrocarbon Decomposition at Low Temperature Synthesis of Graphene Nanocomposites
  • 文献类型:   Article
  • 作  者:   TYNYSHTYKBAYEV K, SPITAS C, KOSTAS K, INSEPOV Z
  • 作者关键词:  
  • 出版物名称:   ECS JOURNAL OF SOLID STATE SCIENCE TECHNOLOGY
  • ISSN:   2162-8769 EI 2162-8777
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1149/2162-8777/abdd86
  • 出版年:   2021

▎ 摘  要

The energy of low-temperature synthesis of graphene on the surface of nanoporous silicon (nc-PS) is considered. It was shown that the energy of low-temperature synthesis of graphene on nc-PS is due to the excess energies of the nanocrystal surface, the interfaces of the nanocrystal nc-Si/c-Si monocrystal matrix, and the free dangling bonds of silicon atoms of nanoscale silicon grains in the skeleton of porous silicon. This opens up a new perspective for the development of methods for the low-temperature synthesis of graphene without metal catalysts for the decomposition of carbon precursors, including the use of the ALD (atomic layer deposition) method.