• 文献标题:   Simple and mass-produced mechanochemical preparation of graphene nanosheet/polyaniline composite assisted with bifunctional ionic liquid
  • 文献类型:   Article
  • 作  者:   LU XJ, DOU H
  • 作者关键词:   polyaniline, graphene nanosheet, ionic liquid, mechanochemical preparation
  • 出版物名称:   FUNCTIONAL MATERIALS LETTERS
  • ISSN:   1793-6047 EI 1793-7213
  • 通讯作者地址:   Xiamen Univ Technol
  • 被引频次:   0
  • DOI:   10.1142/S1793604716500417
  • 出版年:   2016

▎ 摘  要

Graphene nanosheet/polyaniline (GNS/PANI) composite was prepared by a simple and mass-produced mechanochemical method, where the functionalized ionic liquid 1-(3-sulfonic acid) propyl-3-methylimidazolium hydrogen sulfate conducts as not only the dispersant of GNS but also the dopant of PANI. The GNS/PANI composite characterized by Fourier transformation infrared spectra, UV-Vis spectra and X-ray diffraction shows that the resulting PANI in composite is in its doped, conductive emeraldine oxidation state. Scanning electron microscope images reveal that the GNS/PANI composite with PANI uniformly coated on the surface of GNS is randomly stacking. Compared with pure PANI, the GNS/PANI composite has higher electrical conductivity, better thermal stability and electrochemical activity due to the presence of GNS.