• 文献标题:   1-aza-18-crown-6 ether tailored graphene oxide for Cs(I) removal from wastewater
  • 文献类型:   Article
  • 作  者:   LIU P, SHEN Z, CHENG JX, HAN Z, XU WD, JI MB, MA FQ
  • 作者关键词:   crown ether, cs i, graphene oxide, wastewater
  • 出版物名称:   RADIOCHIMICA ACTA
  • ISSN:   0033-8230 EI 2193-3405
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1515/ract-2022-0068 EA OCT 2022
  • 出版年:   2023

▎ 摘  要

Due to the relative abundance, long half-life and high mobility of radioactive cesium (Cs), new adsorbents are urgently needed to treat Cs to ensure public health. In this study, a graphene oxide (GO) based adsorbent for Cs(I) adsorption was prepared by 1-aza-18-crown-6 ether modification. XRD, FT-IR, XPS and SEM results showed that the properties of 1-aza-18-crown 6 ether modified GO (18C6-GO) changed dramatically compared with that of raw graphite. The adsorption properties of 18C6-GO for Cs(I) were studied by batch static adsorption experiments. The results showed that the adsorption equilibrium time of 18C6-GO was 20 h. Kinetic study revealed that the adsorption rate of Cs(I) conformed to pseudo-second-order kinetic model. Langmuir adsorption isotherm simulation indicated that the adsorption arises at homogeneous adsorption sites on 18C6-GO. Therefore, crown ether modified GO may have implications for the treatment of wastewater.