• 文献标题:   Facile fabrication of MnO2 nanorod/graphene hybrid as cathode materials for lithium batteries
  • 文献类型:   Article
  • 作  者:   TU FY, WU TH, LIU SQ, JIN GH, PAN CY
  • 作者关键词:   manganese dioxide, nanorod, graphene, hybrid, lithium batterie
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Cent S Univ
  • 被引频次:   40
  • DOI:   10.1016/j.electacta.2013.05.108
  • 出版年:   2013

▎ 摘  要

A facile thermal annealing method is demonstrated to fabricate the MnO2 nanorods/graphene hybrid. The MnO2 nanorods are well anchored on the graphene, confirmed by the scanning electron microscopy and transmission electron microscopy images. The hybrid annealed at 300 degrees C (MG-300) shows a high initial discharge capacity of 241 mAh g(-1) at 0.1 C with a graphene loading rate of 9%. In addition, it shows good cycling stability and maintains a capacity of 158.3 mAh g(-1) after 100 cycles in the potential window between 2 and 3.5 V. The MG-300 exhibits the best electrochemical performance among all the materials, which is due to the high electronic conductivity of graphene and the MnO2 nanorods which is consisted of gamma-MnO2 and beta-MnO2. (C) 2013 Elsevier Ltd. All rights reserved.