• 文献标题:   In-Situ Construction Molecular Imprinting Electrocatalyst of Au-MoO3/Graphene for Bisphenol A Determination with Long-Term Stability
  • 文献类型:   Article
  • 作  者:   LI Z, ZHANG HM, ZHA QB, LI JH, ZHU MS
  • 作者关键词:   molecular imprinting, moo3, bisphenol a, electrochemical sensor, longterm stability
  • 出版物名称:   CATALYSTS
  • ISSN:  
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.3390/catal13010091
  • 出版年:   2023

▎ 摘  要

Molecular imprinting (MI) technology has been used in electrochemical analysis technology because of its unique selectivity and specificity. In this work, an electrochemical sensor based on in-situ inorganic MI-Au-MoO3/graphene for bisphenol A (BPA) analysis is designed, where MI-MoO3 is hybridized with graphene nanosheets and Au nanoparticles, and BPA is acted as the temple molecular. Differential pulse voltammetry (DPV) was used to evaluate the sensing performance of the MI-Au-MoO3/rGO sensor toward BPA determination and it is about 2.0 times that of NI-Au-MoO3/rGO. The as-constructed sensor presents a wide linear range from 0.01 to 106.04 mu M and a low limit of detection of 0.003 mu M. It also displays outstanding stability and repeatability up to 20 days, and can be used to analyze the content of BPA in dust leachate and plastic bottle. This sensor offers a promising strategy for environment pollution and food analysis via MI technology.