• 文献标题:   Synthesis and Characterization of Functionalized Graphene with KH-570
  • 文献类型:   Article
  • 作  者:   SHI JJ, MA WS, LIN XD
  • 作者关键词:   3glycidoxypropyltrimethoxysilane, graphene oxide, graphene, functionalized
  • 出版物名称:   CHINESE JOURNAL OF INORGANIC CHEMISTRY
  • ISSN:   1001-4861
  • 通讯作者地址:   S China Univ Technol
  • 被引频次:   10
  • DOI:  
  • 出版年:   2012

▎ 摘  要

The graphene oxide (GO) was prepared from natural graphite by the Hummers method, and then was modified by introducing 3-glycidoxypropyltrimethoxysilane (KH-570). The functionalized graphene was subsequently prepared in the presence of hydrazine hydrate. The functionalized graphene can be stably dispersed in ethanol/H2O (9:1, V/V), acetone/H2O (9:1, V/V) or N,N-dimethyl formamide (DMF)/H2O (9:1, V/V). The samples were characterized by using Fourier Transform Infrared Spectroscopy (FTIR), Atomic Force Microscope (AFM), X-ray Photoelectron Spectroscopy (XPS) and X-ray diffraction (XRD). The results show that siloxane of KH-570 reacted with hydroxy group of graphene oxide; the disorder of functionalized graphene increased and the distance between functionalized graphene sheets decreased after the modified graphene oxide was reduced with hydrazine hydrate. Functionalized graphene were exfoliated into single layer or few-layers in DMF/H2O, and the thickness of sheets is between 1.1 nm and 2.3 nm.