• 文献标题:   Effect of electrolyte on the supercapacitive behaviour of copper oxide/reduced graphene oxide nanocomposite
  • 文献类型:   Article
  • 作  者:   RAI S, BHUJEL R, BISWAS J, SWAIN BP
  • 作者关键词:   cupric oxide/reduced graphene oxide, cyclic voltammetry, electrochemical impedance spectroscopy, electrolyte, supercapacitor, capacitance retention
  • 出版物名称:   CERAMICS INTERNATIONAL
  • ISSN:   0272-8842 EI 1873-3956
  • 通讯作者地址:   Natl Inst Technol
  • 被引频次:   5
  • DOI:   10.1016/j.ceramint.2019.04.114
  • 出版年:   2019

▎ 摘  要

Cupric oxide/reduced graphene oxide (CuO/rGO) nanocomposites were synthesized through a chemical reduction method using hydrazine hydrate as the reducing agent. The morphology, elemental composition, and bonding network of the CuO/rGOnanocomposites were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy respectively. The XRD results reveal lattice spacing and lattice strain from 3.371 to 3.428 angstrom and 1.05 x 10(-3) to 5.44 x 10(-3) respectively, with the increasing ratio of rGO: CuO from 1:1 to 1:5. The cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS)and galvanostatic charge-discharge (GCD) studyofCuO/rGOas the electrode material showed excellent super-capacitive behavior in H2SO4 over Na2SO4 electrolytes. Moreover CuO/rGO nanocomposites exhibited better capacitance retention in H2SO4 (75.69%) compared to Na2SO4 (12.06%).