▎ 摘　　要

Confocal micro-Raman spectroscopy is used as a sensitive tool to study the nature of laser-induced defects in single-layer graphene. Appearance and drastic intensity increase of D- and D' modes in the Raman spectra at high power of laser irradiation is related to generation of structural defects. Time-and power-dependent evolution of Raman spectra is studied. The dependence of relative intensity of defective D- and D' bands is analyzed to relate the certain types of structural defects. The surface density of structural defects is estimated from the intensity ratio of D- and G bands using the D- band activation model. Unusual broadening of the D band and splitting of the G band into G(-) and G(+) components with redistribution of their intensities is observed at high laser power and exposition. Position of the G(+) band is discussed in relation with nonuniform doping of graphene with charge impurities. Simultaneous presence in the Raman spectra of heavily irradiated graphene of rather narrow G band and broaden D band is explained by coexistence within the Raman probe of more and less damaged graphene areas. This assumption is additionally confirmed by confocal Raman mapping of the heavily irradiated area.