• 文献标题:   Co9S8@MoS2 core-shell nanostructure anchored on reduced graphene oxide with improved electrochemical performance for lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   REN HB, GU CP, ZHAO JJ, JOO SW, HUANG JR
  • 作者关键词:   mos2, co9s8, coreshell nanostructure, reduced graphene oxide, lithium ion batterie
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Anhui Normal Univ
  • 被引频次:   8
  • DOI:   10.1016/j.apsusc.2018.12.257
  • 出版年:   2019

▎ 摘  要

Co9S8@MoS2 core-shell nanoparticles anchored on both sides of reduced graphene oxide (Co9S8@MoS2/rGO) were synthesized via hydrothermal reaction. The core-shell composites were used as an anode material and demonstrated enhanced electrochemical performance with high capacity, capacity retention, cycling stability, and rate capability during cycling tests. The nanocomposites deliver a reversible capacity of 2014.5 mAh g(-1) at a high rate of 0.3 A g(-1) with a capacity retention efficiency of 82.8% after 200 cycles. The reduced graphene oxide-based three-dimensional framework of the core-shell structure can reduce the internal resistance of the whole electrode, facilitate more Li+ ion insertion and extraction from the crystal structure, and relieve the strain caused by volume change during the lithiation/delithiation process. The electrochemical behaviors could make the composites a great potential anode material for lithium-ion batteries.