• 文献标题:   DNA Induced FePt Bimetallic Nanoparticles on Reduced Graphene Oxide for Electrochemical Determination of Dopamine
  • 文献类型:   Article
  • 作  者:   ZHANG WY, LIU Y
  • 作者关键词:   reduced graphene oxide, fept bimetal nanoparticle, dna, electroanalysi, dopamine
  • 出版物名称:   CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
  • ISSN:   1005-9040 EI 2210-3171
  • 通讯作者地址:   Tsinghua Univ
  • 被引频次:   4
  • DOI:   10.1007/s40242-015-4515-6
  • 出版年:   2015

▎ 摘  要

FePt bimetallic nanoparticles were formed on reduced graphene oxide(rGO) with the help of double-stranded DNA(dsDNA) via a simple and universal route to obtain a FePt/DNA-rGO composite. The FePt nanoparticles with an average size of about 5 nm were well dispersed on rGO. FePt/DNA-rGO modified glassy carbon electrode(GCE) exhibited excellent electrocatalytic activity for the oxidation of dopamine(DA) with a detection limit of 100 nmol/L(S/N = 3). In addition, the FePt/DNA-rGO based electrochemical sensor showed an excellent selectivity for DA in the presence of ascorbic acid(AA), uric acid(UA) and other interference reagents. The as-prepared electrochemical biosensor shows great promise in the application of clinical diagnostics.