• 文献标题:   Ni (II) schiff base complex immobilized on graphene oxide nano-sheets catalyzed epoxidation of alkenes
  • 文献类型:   Article
  • 作  者:   ALLAHRESANI A
  • 作者关键词:   ni ii schiff base complex, epoxidation, tbutyl hydroperoxide, graphene oxide
  • 出版物名称:   JOURNAL OF THE IRANIAN CHEMICAL SOCIETY
  • ISSN:   1735-207X EI 1735-2428
  • 通讯作者地址:   Univ Birjand
  • 被引频次:   4
  • DOI:   10.1007/s13738-017-1054-8
  • 出版年:   2017

▎ 摘  要

Ni (II) schiff base complex was synthesized by the reaction of nickel acetate tetrahydrate with N, N'-Bis(2,4-di-hydroxybenzaldehyde)-1,2-cyclohexanediamine and supported on modified grapheme oxide nano-sheets using 3-chloropropyltrimethoxysilane as a reactive surface modifier. The heterogeneous nano-catalyst was characterized by Fourier transform infrared spectra, X-ray diffraction, thermogravimetric analysis, transmission electron microscopy, nitrogen adsorption-desorption isotherms and atomic absorption spectroscopy. This catalyst was used for the epoxidation of alkenes using tert-butyl hydroperoxide as oxidant, giving excellent conversions and selectivity. The catalyst showed great reusability and selectivity without significant loss of activity in the epoxidation reactions.