• 文献标题:   Considering the effect of graphene loading in water-based epoxy coatings
  • 文献类型:   Article
  • 作  者:   MONETTA T, ACQUESTA A, CARANGELO A, BELLUCCI F
  • 作者关键词:   coating, graphene, nanocomposite, corrosion, epoxy waterbased resin
  • 出版物名称:   JOURNAL OF COATINGS TECHNOLOGY RESEARCH
  • ISSN:   1945-9645 EI 1935-3804
  • 通讯作者地址:   Univ Napoli Federico II
  • 被引频次:   5
  • DOI:   10.1007/s11998-018-0045-8
  • 出版年:   2018

▎ 摘  要

Recently, graphene has gained increasing interest in numerous fields of application and, in particular, it has been used as a nanofiller in the preparation of polymeric composites to improve their mechanical and transport properties. However, the effect of graphene as a potential additive for anticorrosive organic coatings is not widely studied. In this work, low levels of graphene nanosheets, 0.5 and 1wt%, were added to an additive-free waterborne epoxy resin applied to Al2024-T3 aluminum alloy samples. The presence of graphene did not affect the polymerization process of the resin and the adhesion at coating/substrate interface, as demonstrated by experimental results, while showing a slight effect on coatings wettability. Electrochemical analysis revealed an improvement of the protective properties of the coating that could be assigned to a slow absorption rate of the electrolytes in the polymeric matrix and a lesser amount of absorbed water than the unloaded film.