• 文献标题:   CuO ultrathin nanosheets decorated reduced graphene oxide as a high performance anode for lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   PU FZ, KONG CC, LV J, BOMA, ZHANG WQ, ZHANG XJ, YANG S, JIN H, YANG ZM
  • 作者关键词:   energy storage material, oxide material, composite material, oxidation
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   Xi An Jiao Tong Univ
  • 被引频次:   9
  • DOI:   10.1016/j.jallcom.2019.06.160
  • 出版年:   2019

▎ 摘  要

Two-dimensional (2D) nanocomposites, based on graphene and transition metal oxides, hold great promise as high-performance electrode materials for next-generation lithium-ion batteries. Herein, a novel 2D CuO/RGO has been constructed by CuO ultrathin nanosheets and reduced graphene oxides (RGO) through in-situ oxidizing the Cu/RGO nanocomposite with hydrogen peroxide. CuO nanosheets with a thickness of 1.17-1.57 nm are uniformly and tightly anchored on the RGO surface without aggregation and thus the as-prepared CuO/RGO nanosheets electrode show strong interfacial coupling and fast electron transfer. Electrochemical characterizations reveal that the CuO/RGO nanocomposite electrode exhibits a remarkably enhanced cycling performance and rate performance. At the current density of 0.1C, the initial discharge capacity of 811 mAh/g has been delivered by CuO/RGO nanosheets electrode and the coulombic efficiency maintains 99.44% after 100 cycles. Moreover, the CuO/RGO nanosheets exhibit a stable specific capacity of 386 mAh/g after 200 cycles at 3C. In addition, the as-prepared CuO/RGO nanocomposite electrode exhibited excellent rate performance and lower charge transfer resistance. The current study presents a feasible route to fabricate nanosheets electrode materials for next-generation energy storage devices. (C) 2019 Published by Elsevier B.V.