• 文献标题:   Avoiding oxidation with coating: graphene protected magnesium surfaces
  • 文献类型:   Article
  • 作  者:   OLMOSASAR JA, MARISCAL MM
  • 作者关键词:  
  • 出版物名称:   PHYSICAL CHEMISTRY CHEMICAL PHYSICS
  • ISSN:   1463-9076 EI 1463-9084
  • 通讯作者地址:   Consejo Nacl Invest Cient Tecn
  • 被引频次:   0
  • DOI:   10.1039/c9cp02298h
  • 出版年:   2019

▎ 摘  要

Magnesium is a promising material for automotive technology. Avoiding its spontaneous oxidation is, however, mandatory for a feasible industrial application of this metal. We perform computer simulations to demonstrate that a protective graphene layer can successfully avoid the oxidation of a magnesium material. This feature remains true even when the graphene layer has several simple defects, such as vacancies and Stone-Wales transformations. In fact, the defects actually increase the strength of the graphene/metal interaction, further enhancing the protective properties. These results are rationalized in terms of the low Mg cohesive energy, which allows the system to quickly reconstruct and adapt.