• 文献标题:   Production and properties of top-down and bottom-up graphene oxide
  • 文献类型:   Article
  • 作  者:   PONIATOWSKA A, TRZASKOWSKI M, CIACH T
  • 作者关键词:   graphene oxide, hydrothermal method, modified hummers method, fluorescence, pka measurement
  • 出版物名称:   COLLOIDS SURFACES APHYSICOCHEMICAL ENGINEERING ASPECTS
  • ISSN:   0927-7757 EI 1873-4359
  • 通讯作者地址:   Warsaw Univ Technol
  • 被引频次:   6
  • DOI:   10.1016/j.colsurfa.2018.10.049
  • 出版年:   2019

▎ 摘  要

Two known ways of Graphene Oxide (GO) production, "bottom-up" and "top-down" were investigated and their products compared. First one is based on thermal decomposition of citric acid in different conditions while the second is based on the known modified Hummers method, in our case, it is the oxidation and exfoliation of synthetic graphite. The first technique, less known, was investigated deeper to check the influence of process parameters on the yield, size distribution and chemical and physical properties of the obtained bottom-up GO. Both types of products are compared due to their morphology, size distribution, physicochemical properties, acidic properties in water, and fluorescence in various pH conditions in water, all at various production process parameters.