• 文献标题:   Electrocatalytic Activity towards Oxygen Reduction of Electropolymerized Cobalt Porphyrin Doped with Ionic-Liquid-Functionalized Graphene
  • 文献类型:   Article
  • 作  者:   KAPLAN A, SOIFER L, ELIYAHU D, KORIN E, BETTELHEIM A
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF THE ELECTROCHEMICAL SOCIETY
  • ISSN:   0013-4651 EI 1945-7111
  • 通讯作者地址:   Ben Gurion Univ Negev
  • 被引频次:   2
  • DOI:   10.1149/2.0731507jes
  • 出版年:   2015

▎ 摘  要

Electropolymerized films of Coatetetra(4-hydroxyphenyl)porphyrin doped with ionic-liquid-functionalized graphene were obtained by a simple one-step preparation procedure. Spectroscopic (UV-Vis., Raman), microscopic (AFM, SEM), and electrochemical methods were used to characterize the films. The composite films show considerable lower H2O2 yields and at more positive potentials for O-2 reduction, as compared to the undoped ones. Stability during king-term use of films applied on electrodes, including porous ones, allow to consider them as possible non-noble catalyst based O-2 reduction cathodes in fuel cells. (C) 2015 The Electrochemical Society. All rights reserved.