• 文献标题:   Enhancement of peroxidase-like activity of N-doped graphene assembled with iron-tetrapyridylporphyrin
  • 文献类型:   Article
  • 作  者:   MAGERUSAN L, SOCACI C, POGACEAN F, ROSU MC, BIRIS AR, COROS M, TURZA A, FLOAREAVRAM V, KATONA G, PRUNEANU S
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:  
  • 通讯作者地址:   Natl Inst Res Dev Isotop Mol Technol
  • 被引频次:   7
  • DOI:   10.1039/c6ra15414j
  • 出版年:   2016

▎ 摘  要

The paper describes two preparation methods for the non-covalent functionalization of N-doped graphene with iron(III)-tetrapyridylporphyrin. The obtained nanomaterials show enhanced peroxidase-like activity compared to N-doped graphene and effectively oxidize 3,3'-dimethylbenzidine with hydrogen peroxide with the formation of a blue product. The catalytic activity and implicitly the color intensity are dependent on the hydrogen peroxide concentration, thus creating the possibility for its quantification by UV-Vis spectroscopy. In addition, the nanomaterial obtained by direct functionalization was investigated for its catalytic ability to remove bisphenol A from pH neutral water solutions.