• 文献标题:   High Performance PbS Quantum Dot/Graphene Hybrid Solar Cell with Efficient Charge Extraction
  • 文献类型:   Article
  • 作  者:   KIM BS, NEO DCJ, HOU B, PARK JB, CHO Y, ZHANG NL, HONG J, PAK S, LEE S, SOHN JI, ASSENDER HE, WATT AAR, CHA S, KIM JM
  • 作者关键词:   hybrid solar cell, pbs quantum dot, graphene, exciton dissociation, charge transfer
  • 出版物名称:   ACS APPLIED MATERIALS INTERFACES
  • ISSN:   1944-8244
  • 通讯作者地址:   Univ Oxford
  • 被引频次:   32
  • DOI:   10.1021/acsami.6b02544
  • 出版年:   2016

▎ 摘  要

Hybrid colloidal quantum dot (CQD) solar cells are fabricated from multilayer stacks of lead sulfide (PbS) CQD and single layer graphene (SG). The inclusion of graphene interlayers is shown to increase power conversion efficiency by 9.18%. It is shown that the inclusion of conductive graphene enhances charge extraction in devices. Photoluminescence shows that graphene quenches emission from the quantum dot suggesting spontaneous charge transfer to graphene. CQD photodetectors exhibit increased photoresponse and improved transport properties. We propose that the CQD/SG hybrid structure is a route to make CQD thin films with improved charge extraction, therefore resulting in improved solar cell efficiency.