• 文献标题:   Enhancement of the Electrochemical Performance of LiNi1/3Co1/3Mn1/3O2 Cathode Material by Double-Layer Coating with Graphene Oxide and SnO2 for Lithium-Ion Batteries
  • 文献类型:   Article
  • 作  者:   MA YX, CUI P, ZHAN D, GAN B, MA YL, LIANG Y
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF NANOMATERIALS
  • ISSN:   1687-4110 EI 1687-4129
  • 通讯作者地址:   Hubei Univ Arts Sci
  • 被引频次:   1
  • DOI:   10.1155/2019/7586790
  • 出版年:   2019

▎ 摘  要

The graphene oxide-coated SnO2-Li1/3Co1/3Mn1/3O2 (GO-SnO2-NCM) cathode material was successfully synthesized via a facile wet chemical method. The pristine NCM and GO-SnO2-NCM were characterized by X-ray diffraction, scanning electron microscopy, energy-dispersive spectroscopy, transmission electron microscopy, and X-ray photoelectron spectroscopy. The results showed that the double-coating layer did not destroy the NCM crystal structure, with multiple nano-SnO2 particles and GO uniformly covering the NCM surface. Electrochemical tests indicated that GO-SnO2-NCM exhibited excellent cycling performance, with 90.7% capacity retention at 1C after 100 cycles, which was higher than 74.3% for the pristine NCM at the same cycle. The rate capability showed that the double-coating layer enhanced surface electronic-ionic transport. Electrochemical impedance spectroscopy results confirmed that the GO-SnO2-coating layer effectively suppressed the increased electrode polarization and charge transfer resistance during cycling.