▎ 摘　　要

Advanced hierarchical hybrid nanostructures of polar, conductive and catalytic chemical traps/carbon with rationally tailored components, structures, and chemistries are important in determining the performance of lithium-sulfur (Li-S) batteries. Herein we propose a facile strategy to prepare 3D-structured CNF@graphene-CoSe (CNF@G(L)-CoSe) cable/sheath heterostructure with the in-situ formed CoSe as a catalyst for graphene-like carbon growth and Se as a catalyst promoter. The architecture integrates high electrical conductivity, effective ion transport, notable polysulfide entrapment, and polysulfide redox kinetics, availing lithium/sulfur conversion when applied as an interlayer in a Li-S battery. As expected, the battery delivered a low decay of 0.053% per cycle over 700 cycles at 1 C. The capacity even remained 649.4 and 524.5 mA h g(-1) at 4 and 6 C, respectively. Furthermore, an areal capacity of about 3 mA h cm(-2) at 0.1 C after long-term tests can still maintain with sulfur loading of 4.5 mg cm(-2).