• 文献标题:   The role and importance of surface modification of polyester fabrics by chitosan and hexadecylpyridinium chloride for the electrical and electro-thermal performance of graphene-modified smart textiles
  • 文献类型:   Article
  • 作  者:   MIANKAFSHE MA, BASHIR T, PERSSON NK
  • 作者关键词:  
  • 出版物名称:   NEW JOURNAL OF CHEMISTRY
  • ISSN:   1144-0546 EI 1369-9261
  • 通讯作者地址:   Univ Boras
  • 被引频次:   7
  • DOI:   10.1039/c8nj05445b
  • 出版年:   2019

▎ 摘  要

Graphene has the potential to create highly valuable electrical conductive textile systems with maintained pliability and psychological comfort. There have already been numerous studies regarding electrically functionalized graphene-coated textiles. However, processing development is far from being exhausted. Here we have studied electro-thermal textiles based on the most common fibers, polyester, and an industry-relevant graphene impregnation method by introducing surface pre-modification of fabrics for graphene-modified textile processing. For this purpose, polyester fabrics were treated with four different cationic agents and impregnated with graphene oxide (GO) colloidal particles. Then, direct chemical reduction of GO to an electrically conductive graphene oxide (rGO) was performed. A pristine fabric modified by rGO showed a high resistance of 27.3 k (-1) without any electro-thermal activity, whilst chitosan-treated (CS) and hexadecylpyridinium chloride-treated (HDPC) fabrics had resistance values of 2.7 and 0.59 k (-1) respectively, and excellent heat propagation with a good temperature distribution. The steady-state temperature of CS-treated and HDPC-treated fabrics increased from 28 degrees C and 33 degrees C to 60 degrees C and 120 degrees C, respectively, as the voltage applied increased from 10 V to 30 V. These rGO-modified fabrics also have excellent electro-mechanical performance, and are good candidates for flexible strain sensor applications.