• 文献标题:   Enhancement of electrical conductivity of hydrazine-reduced graphene oxide under thermal annealing in hydrogen atmosphere
  • 文献类型:   Article
  • 作  者:   RUDENKO RM, VOITSIHOVSKA OO, POROSHIN VN
  • 作者关键词:   carbon material, reduced graphene oxide, electrical propertie, variable range hopping conduction, heat treatment
  • 出版物名称:   MATERIALS LETTERS
  • ISSN:   0167-577X EI 1873-4979
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1016/j.matlet.2022.133476 EA NOV 2022
  • 出版年:   2023

▎ 摘  要

The effect of further thermal annealing in a hydrogen atmosphere on the electrical properties of hydrazine -reduced graphene oxide (RGO) was investigated. It was found that heat treatment significantly improves the conductivity of RGO and reduces the room temperature resistivity by ten times. The changes become even more significant at the temperature decrease to 4.2 K and can exceed five orders. The variable range hopping con-duction mechanism is the major charge transfer in the RGO at low temperatures for all annealing temperatures in the hydrogen of 100-800 degrees C. It is shown that the characteristic temperature T0 of the hopping transport exhibits an exponential decrease with an increase in the annealing temperature. Low-temperature studies of electric charge transfer reveal that the unified activation energy accompanying the improvement in conductivity is 0.3 eV.