• 文献标题:   Reduced graphene oxide cross-linked L-cysteine modified glassy carbon electrode for detection of environmental pollutant of hydroquinone
  • 文献类型:   Article
  • 作  者:   XIA Y, WANG KQ, SHI Y, GUI XC, LV CN, TAO HS
  • 作者关键词:   graphene oxide, lcysteine, sensor, hydroquinone
  • 出版物名称:   FLATCHEM
  • ISSN:   2452-2627
  • 通讯作者地址:  
  • 被引频次:   9
  • DOI:   10.1016/j.flatc.2020.100214
  • 出版年:   2021

▎ 摘  要

With the social and economic development, environmental pollution issues have gradually become a serious threat to ecosystem. Therefore, effective detection methods of environmental pollutants have been widely expanded. In this study, an electrochemical sensor based on a functioned graphene was constructed. The functional graphene was obtained by electrochemical deposition of L-cysteine on graphene oxide modified glassy carbon electrode. The composite on the modified glassy carbon electrode was characterized by scanning electron microscopy, transmission electron microscopy and X-ray photoelectron spectroscopy. The characterized results discovered that graphene oxide was reduced and cross-linked to L-Cys simultaneously, with a corrugated sheet structure. The electrochemical behavior of the electrode was investigated by electrochemical impedance spectroscopy and cyclic voltammetry, and proved that the electrode has a rapid transfer of electrons and a good catalytic effect on environmental pollutant of hydroquinone. The constructed electrode can be used to detect hydroquinone, with the detection limit of 1.5 mu M (S/N = 3), and a good linear relationship in the range of 2-160 mu M. The low relative standard deviation of identical sensors and good anti-interference for coexisting matters revealed that the sensor has an important theoretical significance and broad application prospect.