• 文献标题:   Direct analysis of ascorbic acid in food beverage samples by flow injection analysis using reduced graphene oxide sensor
  • 文献类型:   Article
  • 作  者:   DE FARIA LV, LISBOA TP, DE FARIAS DM, ARAUJO FM, MACHADO MM, DE SOUSA RA, MATOS MAC, MUNOZ RAA, MATOS RC
  • 作者关键词:   ascorbic acid, reduced graphene oxide, flow injection analysi, vitamin c, food sample
  • 出版物名称:   FOOD CHEMISTRY
  • ISSN:   0308-8146 EI 1873-7072
  • 通讯作者地址:   Univ Fed Juiz de Fora
  • 被引频次:   4
  • DOI:   10.1016/j.foodchem.2020.126509
  • 出版年:   2020

▎ 摘  要

In this paper, a simple, sensitive and precise electroanalytical method was developed using flow injection analysis (FIA) with amperometric detection and reduced graphene oxide sensor for ascorbic acid determination in samples of multivitamin beverages, milk, fermented milk, and milk chocolate. The advantages of this sensor include a potential displacement of 450 mV and a 2-fold peak current increase for electrochemical oxidation of ascorbic acid, which resulted in a highly sensitive method. No interference of sample matrix was observed, avoiding solvent extraction procedures (samples were only diluted). The FIA allowed a high analytical frequency, approximately 96 injections per hour, together with adequate detection limit of 4.7 mu mol L-1. Good precision (RSD < 7%) and accuracy (recoveries between 91 and 108%) evidenced the robustness of the method. The method was compared with ultra-fast liquid chromatography (UFLC) obtaining statistically similar results (95% confidence level). The ascorbic acid content in samples varied from 0.065 to 2.53 mmol L-1.