• 文献标题:   One-pot synthesis of amine-functionalized graphene oxide by microwave-assisted reactions: an outstanding alternative for supporting materials in supercapacitors
  • 文献类型:   Article
  • 作  者:   CALIMAN CC, MESQUITA AF, CIPRIANO DF, FREITAS JCC, COTTA AAC, MACEDO WAA, PORTO AO
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Fed Univ Espirito Santo UFES
  • 被引频次:   14
  • DOI:   10.1039/c7ra13514a
  • 出版年:   2018

▎ 摘  要

A simple and straightforward method using microwave-assisted reactions is presented for the functionalization of graphene oxide with aromatic and non-aromatic amines, notedly dibenzylamine (DBA), p-phenylenediamine (PPD), diisopropylamine (DPA) and piperidine (PA). The as-synthesized amine-functionalized graphene oxide materials (amine-GO) were characterized using spectroscopic techniques including XRD, FTIR, C-13 NMR, XPS, TEM for imaging and thermogravimetric analysis (TGA). The characterization confirmed the functionalization for all amines, reaching relatively high surface nitrogen atomic concentrations of up to 8.8%. The investigations of electrochemical behavior for the amine-GOs show the significant improvement in GO's electrochemical properties through amine functionalization, exhibiting long life cycle stability and reaching specific capacitance values of up to 290 F g(-1) and 260 F g(-1) for GO-PA and GO-DPA samples, respectively, confirming their potential application as alternative supporting materials in supercapacitors.