• 文献标题:   Electrochemical alternative to obtain reduced graphene oxide by pulse potential: Effect of synthesis parameters and study of corrosion properties
  • 文献类型:   Article
  • 作  者:   LOPEZOYAMA AB, DOMINGUEZCRESPO MA, TORRESHUERTA AM, ONOFREBUSTAMANTE E, GAMEZCORRALES R, CAYETANOCASTRO N
  • 作者关键词:   graphite, graphene oxide, electrochemically reduced graphene oxide, corrosion resistance
  • 出版物名称:   DIAMOND RELATED MATERIALS
  • ISSN:   0925-9635 EI 1879-0062
  • 通讯作者地址:   Inst Politecn Nacl
  • 被引频次:   2
  • DOI:   10.1016/j.diamond.2018.04.014
  • 出版年:   2018

▎ 摘  要

Two methods to form reduced graphene oxide (rGO) coatings are proposed as simple, rapid and reproducible alternatives to protect 304 L SS substrates. The first route combines traditional Hummers' modified method and pulse electrodeposition technique (-1.6 and -2 V-SCE) whereas with the second one, reduction is obtained by applying the potentiostatic method (-1 to -4 V-SCE) in a solution containing graphite + H2SO4. The electrochemical results show that ERGO coatings can properly protect metallic substrates only when they are obtained with an applied potential of -4 V-SCE. To carry out this process, strong oxidants, extensive water amounts and long reaction times are avoided.