▎ 摘　　要

Thin-film composite mixed matrix membranes (CMMMs) were fabricated using interfacial polymerization to achieve high permeance and selectivity for CO2 separation. This study revealed the role of substrate properties on performance, which are not typically considered important. In order to enhance the affinity between the substrate and the coating solution during interfacial polymerization and increase the selectivity of CO2, a mixture of polyethylene glycol (PEG) and dopamine (DOPA) was subjected to a spinning process. Then, the surface of the substrate was subjected to interfacial polymerization using polyethyleneimine (PEI), trimesoyl chloride (TMC), and sodium dodecyl sulfate (SDS). The effect of adding SDS as a surfactant on the structure and gas permeation properties of the fabricated membranes was examined. Thin-film composite hollow fiber membranes containing modified graphene oxide (mGO) were fabricated, and their characteristics were analyzed. The membranes exhibited very promising separation performance, with CO2 permeance of 73 GPU and CO2/N-2 selectivity of 60. From the design of a membrane substrate for separating CO2, the CMMMs hollow fiber membrane was optimized using the active layer and mGO nanoparticles through interfacial polymerization.