• 文献标题:   Photo-anode surface modification using novel graphene oxide integrated with methylammonium lead iodide in organic-inorganic perovskite solar cells
  • 文献类型:   Article
  • 作  者:   VELU KS, ALAM M, AHMAD N, ESAKKIMUTHU S, KUMAR GV, MOHANDOSS S, RAJ JA, SELVAM K, KALITA G, STALIN T
  • 作者关键词:   graphene oxide, methylammonium lead iodide, modification, photoanode, perovskite solar cell
  • 出版物名称:   JOURNAL OF PHYSICS CHEMISTRY OF SOLIDS
  • ISSN:   0022-3697 EI 1879-2553
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.1016/j.jpcs.2021.110036 EA MAR 2021
  • 出版年:   2021

▎ 摘  要

The novel graphene oxide sheet-methylammonium lead iodide (GO-MAPbI(3)) was used as photoanode surface modification and is used as a photosensitizer for perovskite solar cells. The multi-crystalline presence of GO-MAPbI(3)-prepared photo-anode surface and surface morphologies were observed by high-resolution electron transmission microscopy and electron scanning microscopy. The selected electron diffraction pattern of GOMAPbI(3) has also been observed in a multi-crystalline nature. GO-MAPbI(3) containing the elementary composition was determined using X-ray photoelectron spectroscopy. They consist of Pb 4f(5/ 2) and Pb 4f(7/ 2) and have an energy binding value of 143.9 (eV) and 138.9 (eV). GO-MAPbI(3) was a crystalline cubic black color confirmed by an Xray diffraction pattern. From the Fourier transform infrared spectra, graphene oxide functional groups, methylammonium lead iodide internal hydrogen bonding between the C-N group attached to the C-H group and its corresponding values. The photo-current density-voltage curves are regulated by GO-MAPbI(3) coated on a photoanode giving 8.39% of the power conversion efficiency.