• 文献标题:   Improved hydrogen production from formic acid under ambient conditions using a PdAu catalyst on a graphene nanosheets-carbon black support
  • 文献类型:   Article
  • 作  者:   QIN YL, WANG JW, WU YM, WANG LM
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Changchun Inst Appl Chem
  • 被引频次:   20
  • DOI:   10.1039/c4ra05379f
  • 出版年:   2014

▎ 摘  要

Formic acid (FA) has great potential as a suitable liquid source for hydrogen and hydrogen storage materials, provided highly active and selective dehydrogenation catalysts under ambient conditions are developed. Here, well-dispersed bimetallic gold-palladium (PdAu) nanoparticles (NPs) grown on graphene nanosheets-carbon black (GNs-CB) composite supports are synthesized via a facile co-reduction method, wherein the GNs-CB composite support proved to be a powerful dispersion agent and a distinct support for the PdAu NPs. Interestingly, the resultant PdAu/GNs-CB catalyst manifests high selectivity and exceedingly high activity to complete the decomposition of FA at room temperature.