• 文献标题:   Recovery of hydroxytyrosol onto graphene oxide nanosheets: Equilibrium and kinetic models
  • 文献类型:   Article
  • 作  者:   SAHIN S, CIGEROGLU Z, OZDEMIR OK, BILGIN M, ELHUSSEIN E, GULMEZ O
  • 作者关键词:   nanomaterial, graphene oxide, adsorption, biophenol, hydroxytyrosol, olive mill wastewater
  • 出版物名称:   JOURNAL OF MOLECULAR LIQUIDS
  • ISSN:   0167-7322 EI 1873-3166
  • 通讯作者地址:   Istanbul Univ Cerrahpasa
  • 被引频次:   3
  • DOI:   10.1016/j.molliq.2019.04.097
  • 出版年:   2019

▎ 摘  要

In this study, a novel nanomaterial, graphene oxide (GO), which has never been used as an adsorbent in the separation of hydroxytyrosol (HT), has been utilized. GO nanosheets were synthesized by graphite oxidation naturally, which is known as modified Hummer's method. Then, the material obtained was characterized by Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD) methods. Adsorption of HT from aqueous media onto synthesized GO was found to be >85% under optimum conditions (with 0.01 mg GO in 10 mL of solution at 150 rpm for 1440 min, where pH is 9). On the other hand, equilibrium (Langmuir, Freundlich, Temkin, Dubinin-Radushkevich and Redlich-Peterson) and kinetic (pseudo-first order, pseudo-second order, Elovich and intra-particle diffusion) models have been applied for analysis and representation of data. Thermodynamic findings point out that the related adsorption system is exothermic, applicable and spontaneous. (C) 2019 Elsevier B.V. All rights reserved.