• 文献标题:   Reduced Graphene Oxide/Carbon Nanotube/Gold Nanoparticles Nanocomposite Functionalized Screen-Printed Electrode for Sensitive Electrochemical Detection of Endocrine Disruptor Bisphenol A
  • 文献类型:   Article
  • 作  者:   WANG YC, COKELILER D, GUNASEKARAN S
  • 作者关键词:   environmental monitoring, food safety, graphene, electrodeposition, electrochemical reduction, electrochemical sensor
  • 出版物名称:   ELECTROANALYSIS
  • ISSN:   1040-0397 EI 1521-4109
  • 通讯作者地址:   Univ Wisconsin
  • 被引频次:   24
  • DOI:   10.1002/elan.201500120
  • 出版年:   2015

▎ 摘  要

We fabricated a highly sensitive electrochemical sensor for the determination of bisphenol A (BPA) in aqueous solution by using reduced graphene oxide (RGO), carbon nanotubes (CNT), and gold nanoparticles (AuNPs)-modified screen-printed electrode (SPE). GO/CNT nanocomposite was directly reduced to RGO/CNT on SPE at room temperature. AuNPs were then electrochemically deposited in situ on RGO/CNT-modified SPE. Under optimized conditions, differential pulse voltammetry (DPV) produced linear current responses for BPA concentrations of 1.45 to 20 and 20 to 1,490 nM, with a calculated detection limit of an ultralow 800 pM. The sensor response was unaffected by the presence of interferents such as phenol, p-nitrophenol, pyrocatechol, 2,4-dinitrophenol, and hydroquinone.