• 文献标题:   A sensitive voltammetric sensor for taxifolin based on graphene nanosheets with certain orientation modified glassy carbon electrode
  • 文献类型:   Article
  • 作  者:   WANG F, WU YJ, LU K, YE BX
  • 作者关键词:   graphene oxide, pulse potential, voltammetric sensor, taxifolin
  • 出版物名称:   SENSORS ACTUATORS BCHEMICAL
  • ISSN:   0925-4005
  • 通讯作者地址:   Henan Inst Engn
  • 被引频次:   14
  • DOI:   10.1016/j.snb.2014.11.008
  • 出版年:   2015

▎ 摘  要

The electrodeposition of reduced graphene oxide (ERGO) film with preferred vertical orientation was fabricated on a glassy carbon electrode by using pulse potential method in a graphene oxide colloidal solution. Using square wave adsorptive stripping voltammetry (SWASV), the ERGO film was applied for the first time, in developing a high-sensitive electrochemical sensor for detection of taxifolin. Compared with bare glassy carbon electrode (GCE), the resulting electrodes (ERGO/GCE) exhibited excellent response toward the redox of taxifolin by significantly enhancing the redox peak currents and decreasing the peak-to-peak separation. Under the selected conditions, the peak currents were linear relationship with taxifolin concentration in the range of 1.0 x 10(-8)-1.0 x 10(-6)mol L-1, with detection limit of 2.0 x 10(-9)mol L-1. Besides, the ERGO/GCE also exhibited an excellent selectivity, stability, reproducibility and repeatability. (C) 2014 Elsevier B.V. All rights reserved.