• 文献标题:   Sulfonation of graphene nanosheet-supported platinum via a simple thermal-treatment toward its oxygen reduction activity in acid medium
  • 文献类型:   Article
  • 作  者:   HUNG TF, WANG B, TSAI CW, TU MH, WANG GX, LIU RS, TSAI DP, LO MY, SHY DS, XING XK
  • 作者关键词:   sulfonation, graphene, platinum catalyst, in situ chemical reaction, thermal treatment, oxygen reduction reaction
  • 出版物名称:   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
  • ISSN:   0360-3199
  • 通讯作者地址:   Natl Taiwan Univ
  • 被引频次:   16
  • DOI:   10.1016/j.ijhydene.2012.07.027
  • 出版年:   2012

▎ 摘  要

The sulfonated graphene nanosheet-supported platinum (s-Pt/GNS) catalyst synthesized via a simple thermal-treatment in the presence of concentrated sulfuric acid was reported in this study. Influence of sulfonation on its structural, surface, morphological and catalytic characteristics of as-prepared s-Pt/GNS was explored using X-ray diffractometer, Raman spectrometry, zeta potential analyzer, scanning and transmission electron microscopes, and cyclic voltammetry. For the oxygen reduction reaction, the current density generated from the s-Pt/GNS at 0.6 V was approximately 32.5 A g(-1) Pt, which was about 193% higher than that of original Pt/GNS. Copyright (C) 2012, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.