▎ 摘　　要

Lithium metal batteries have been regarded as typical representatives of high-energy storage systems. However, lithium dendrite growth and a fragile solid electrolyte interface (SEI) lead to safety issues and unsatisfactory performances. We tackle the above issues with a dual protection strategy by designing a silver (Ag) decorated F-doped graphene (Ag@FG) matrix. Ag@FG was synthesized by a one-step "ion atmosphere" method. When used as a current collector, Ag@FG shows a low nucleation overpotential and a long cycle life due to the enhanced lithiophilicity, high conductivity of the matrix, and the LiF-enriched SEI. The decorated Ag nanoparticles increased the lithiophilicity of the graphene matrix to induce the uniform deposition of lithium. The doped F leads to the formation of a stable SEI. Thus, Ag@FG shows a low nucleation overpotential of only 8 mV at 0.5 mA cm(-2) and long-term stability for over 1600 h at 1.0 mA cm(-2) and 1.0 mA h cm(-2). The assembled full batteries with LFP also indicate its practicability with good cycling stability and rate capability.