• 文献标题:   Preparation of polyoxazoline-modified reduced graphene oxide and its incorporation into silica
  • 文献类型:   Article
  • 作  者:   ABDULLAH N, HIRATA K, HATANO K, ITOH T, KUBO M, KOSHIO A, KOKAI F
  • 作者关键词:   reduced graphene oxide, polyoxazoline, silica, hybrid
  • 出版物名称:   POLYMER BULLETIN
  • ISSN:   0170-0839 EI 1436-2449
  • 通讯作者地址:   Mie Univ
  • 被引频次:   1
  • DOI:   10.1007/s00289-015-1321-8
  • 出版年:   2015

▎ 摘  要

Amino-terminated poly(2-methyl-2-oxazoline) (PMeOXz-NH2) was synthesized using the living cationic ring-opening polymerization of 2-methyl-2-oxazoline (MeOXz). PMeOXz chains were introduced onto graphene oxide (GO) by the condensation reaction between GO and PMeOXz-NH2 to give PMeOXz-grafted GO (PMeOXz-g-GO), which was converted to PMeOXz-grafted reduced graphene oxide (PMeOXz-g-rGO) by hydrazine reduction. Acid-catalyzed sol-gel method of tetraethoxysilane was carried out in the presence of PMeOXz-g-rGO to give a transparent PMeOXz-g-rGO/SiO2 hybrid retaining the optical property of rGO.