• 文献标题:   The effect of the NH3 activation temperature of graphene/carbon composite nanofibers on their NO catalytic oxidation performance at room temperature
  • 文献类型:   Article
  • 作  者:   GUO ZY, HUANG ZH, KANG FY
  • 作者关键词:   graphene oxide, electrospinning, nh3 treatment, nitric oxide, catalytic oxidation
  • 出版物名称:   NEW CARBON MATERIALS
  • ISSN:   1007-8827 EI 1872-5805
  • 通讯作者地址:   Tsinghua Univ
  • 被引频次:   0
  • DOI:   10.1016/j.carbon.2017.08.053
  • 出版年:   2017

▎ 摘  要

N-doped graphene/carbon composite porous nanofibers were prepared by electrospinning, followed by carbonization in nitrogen and activation in NH3 at 900, 1 000, 1 100 and 1 200 degrees C for 20 min, using polyacrylonitrile as a carbon precursor and graphene oxide as an additive. Their NO (50 ppm) adsorption and catalytic oxidation performances at room temperature were tested. Results showed that the catalytic oxidation activity increased with the activation temperature and a maximum conversion of 49. 7% was achieved for the sample activated at 1 200 degrees C The adsorption capacity for NO and NO2 depended on their specific surface areas. The nitrogen-containing functional groups introduced by NH3 and the active sites formed in graphene sheets jointly increased NO conversion at room temperature.