▎ 摘　　要

Hierarchically stacked graphene oxide (GO) membranes have sparked considerable interest due to their prominent separation performance; however, the underlying separation mechanisms remain elusive. In this study, we conducted molecular dynamics (MD) simulations to explore the role of interlayer distance and pore offset in gas (H-2, CH4, N-2 and CO2) permeation through double-layer GO membranes. Gas permeance is found to increase with the interlayer distance and pore offset until the interlayer distance exceeds a critical value. With elongating the interlayer distance and pore offset, a sieving effect occurs to overcome preferential adsorption and dominates the transport in mixed H-2/CO2, resulting in selective permeation shifting from CO2 to H-2. This simulation study provides mechanistic insight into gas permeation through layered GO membranes, and would facilitate the design of new GO membranes for high-performance gas separation.