• 文献标题:   TiO2-reduced graphene oxide nanocomposite for high-rate application of lithium ion batteries
  • 文献类型:   Article
  • 作  者:   ZHENG CC, HE CH, ZHANG HY, WANG WG, LEI XL
  • 作者关键词:   reduced graphene oxide, tio2, nanocomposite, lithiumion battery
  • 出版物名称:   IONICS
  • ISSN:   0947-7047 EI 1862-0760
  • 通讯作者地址:   Guangdong Univ Technol
  • 被引频次:   9
  • DOI:   10.1007/s11581-014-1175-3
  • 出版年:   2015

▎ 摘  要

TiO2-reduced graphene oxide nanocomposite has been synthesized by a facile hydrothermal process. The structure and morphology have been characterized by X-ray diffraction and scanning electron microscopy. The result shows that a unique nanocomposite has been obtained with the TiO2 nanoparticle homogenously dispersed onto the reduced graphene oxide sheets. The electrochemistry performance has been tested through cyclic voltammetry, constant current discharge/charge tests, and electrochemical impedance techniques. The initial lithium ion storage capacity is 368 mAhg(-1) at the rate of 10 mAg(-1), which exceeds the theoretical capacity value of the anatase TiO2 (335 mAhg(-1)). The nanocomposite exhibits good high-rate capacity of 136.1 mAhg(-1) at rate of 1,000 mAg(-1), and, after 100 cycles, the coulombic efficiency is still maintained as high as 98.6 %. The high specific capacity and good stability can be attributed to the unique structures and make the nanocomposite a promising substitute of the current commercial graphite anode in high-power, high-rate application of lithium ion batteries.