• 文献标题:   Nickel loaded graphene-like carbon hydrogen evolution reaction sheets an improved electrocatalyst for hydrogen evolution reaction
  • 文献类型:   Article
  • 作  者:   XU YG, ULLAH N, CHEN LL, WEI W, OLUIGBO CJ, XIE M, ZHANG MM, XIE JM
  • 作者关键词:   electrocatalyst, hydrogen evolution reaction, ni, graphenelike carbon sheet
  • 出版物名称:   MATERIALS CHEMISTRY PHYSICS
  • ISSN:   0254-0584 EI 1879-3312
  • 通讯作者地址:   Jiangsu Univ
  • 被引频次:   9
  • DOI:   10.1016/j.matchemphys.2019.01.066
  • 出版年:   2019

▎ 摘  要

In this article, we successfully prepare Ni loaded graphene-like carbon sheets which act as an efficient electrocatalyst for hydrogen evolution reaction. The as-prepared electrocatalysts show an ultrathin rose petal-like carbon sheets structure loaded with micro and nano-sized Ni particles. The electrocatalytic activity of Ni loaded carbon sheets electrocatalysts are studied in 1 M KOH solution. Ni-GCS-2 shows overpotential of 0.205 V (vs RHE) at a current density of 10 mA cm(-2) with better stability for 4 h continuously and lower R-ct. Ni-GCS-2 shows only 15% loss for HER after 4 h. The effect of Ni on electrocatalytic performance was investigated. The Ni Nano particles are the active sites for the reaction and graphene-like carbon sheets facilitate electron transport due to their conductive nature. This study showed that Ni-GCS-2 is better in performance as compared to other as prepared electrocatalyst and previously studied Ni-based electrocatalysts.