▎ 摘　　要

Electron transfer capability as crucial properties of anode is directly related to electrocatalytic performance. However, the contributions of electron transfer were always under estimated due to the ambiguous mechanism of electrocatalysis. In this paper, a new electron transfer bridge was constructed in Ni3(HTTP)2/GO to provide a new insight into electrocatalytic performance enhancement. The contributions of active sites candidates, including metal sites, ligands (metal bridging atoms), and electron transfer bridges were innovatively separated. As replacement experimental results (of metal sites and metal bridging atoms), both metal sites and metal bridging atoms contributed slightly as the active center directly for the electrocatalytic degradation of tetracy-cline hydrochloride (TCH). The great improvement was attributed to the generation of "GO-C-O-S-C-Ni3(HTTP)2" bridges, in which S atoms from ligands were critical anchoring sites for the connection of two 2D layers (Ni3(HTTP)2 and GO layer). The experimental and density functional theory results showed Ni3(HTTP)2 could donate electrons to GO layers, leading the electrostatic imbalance of charge density to facilitate electron with-drawal from pollutions (not only TCH, but also dyes and complex microbial flora). The results of this paper provide a new strategy for improving electrocatalytic efficiency by adjusting electron transfer for novel practical applications of Ni3(HTTP)2/GO composites.