• 文献标题:   In situ preparation of manganese sulfide on reduced graphene oxide sheets as cathode for rechargeable aqueous zinc-ion battery
  • 文献类型:   Article
  • 作  者:   MA SC, SUN M, SUN BY, LI D, LIU WL, REN MM, KONG FG, WANG SJ, GUO ZX
  • 作者关键词:   manganese sulfide, composite material, high capacity, zincion batterie, cathode material
  • 出版物名称:   JOURNAL OF SOLID STATE CHEMISTRY
  • ISSN:   0022-4596 EI 1095-726X
  • 通讯作者地址:  
  • 被引频次:   9
  • DOI:   10.1016/j.jssc.2021.122166 EA APR 2021
  • 出版年:   2021

▎ 摘  要

Zinc-ion batteries have been received extensive interest in the resulting energy storage devices due to their high safety, simple operation, environment friendliness and nontoxicity. Herein, we report a composite material of manganese sulfide/reduced graphene oxide (MnS/RGO) as the cathode materials for aqueous zinc-ion batteries, which exhibits excellent cycling performance. Owing to the synergistic effect of desirable structural characteristic of MnS microsphere and favorable conductivity of the graphene network, the composite material delivers remarkable zinc storage performance. The MnS/RGO electrode exhibits a reversible discharge capacity of 289 mA h g(-1) at 100 mA g(-1), and impressive rate capability of 62 mA h g(-1) at 1000 mA g(-1). The brilliant electrochemical performance of MnS/RGO is related to the RGO nanosheets, which greatly improves the electrical contact and effectively alleviates the huge volume expansion during charging and discharging.