• 文献标题:   Removal of phenol and beta-naphthol from aqueous solution by decorated graphene oxide with magnetic iron for modified polyrhodanine as nanocomposite adsorbents: Kinetic, equilibrium and thermodynamic studies
  • 文献类型:   Article
  • 作  者:   PARVIN N, BABAPOOR A, NEMATOLLAHZADEH A, MOUSAVI SM
  • 作者关键词:   polyrhodanine, graphene oxide, phenol, betanaphthol, adsorption
  • 出版物名称:   REACTIVE FUNCTIONAL POLYMERS
  • ISSN:   1381-5148 EI 1873-166X
  • 通讯作者地址:   Univ Mohaghegh Ardabili
  • 被引频次:   0
  • DOI:   10.1016/j.reactfunctpolym.2020.104718
  • 出版年:   2020

▎ 摘  要

This research focuses on the batch adsorption efficiency of magnetic adsorbents for removal both for phenol and beta-naphthol from aqueous solution. Two kinds of nano-adsorbents were investigated: magnetic/polyrhodanine (Fe3O4/PRd) and graphene oxide-magnetic/polyrhodanine (GO-Fe3O4/PRd). GO can improve to be the best nano-adsorbent for phenol and beta-naphthol removal due to its large specific surface areas with a maximum adsorption capacity of 191.0 and 226.2 mg g(-1), respectively, at contact time 15 min. The characterization of prepared nano-adsorbents by XRD, FESEM, FTIR, VSM, EDS, and BET analysis. The kinetic models indicated that the adsorption process followed a Pseudo-Second-Order model, and the Freundlich and Langmuir isotherm models described the adsorption behavior of phenol and beta-naphthol by Fe3O4/PRd and GO-Fe3O4/PRd nanoadsorbents, respectively. Also, thermodynamic studies for both nano-absorbents showed that the absorbing process is an endothermic, spontaneous, and desirable reaction.