• 文献标题:   Novel synthesis of graphene oxide with polystyrene for the adsorption of toluene, ethylbenzene and xylenes from wastewater
  • 文献类型:   Article
  • 作  者:   AZIZI A, TORABIAN A, MONIRI E, HASSANI AH, PANAHI HA
  • 作者关键词:   graphene oxide, polystyrene, tex, isotherm, kinetic, regeneration
  • 出版物名称:   DESALINATION WATER TREATMENT
  • ISSN:   1944-3994 EI 1944-3986
  • 通讯作者地址:   Univ Tehran
  • 被引频次:   2
  • DOI:   10.5004/dwt.2017.20585
  • 出版年:   2017

▎ 摘  要

The main goal of this research was to evaluate the adsorption capacity of toluene, ethylbenzene and xylenes (TEX) onto graphene oxide nanoparticles grafted with polystyrene (GO-PS). Graphene oxide was polymerized using ammonium persulfate initiator. The properties of adsorbents were analyzed by Fourier transform infrared resonance spectroscopy, energy-dispersive X-ray spectroscopy, scanning electron microscopy and Brunauer-Emmett-Teller analysis. This paper includes the elements affective adsorption of TEX such as contact time, pH and adsorbent dose. The adsorption capacity was enhanced with the increasing of contact time and adsorbent dose, but changed insignificantly with pH. The findings demonstrated that an optimum TEX removal efficiency was achieved at contact time of 30 min and adsorbent dose of 1 g/L at 20 mg/L initial TEX concentration (solution pH = 7). The different models were applied to predict the mechanisms of adsorption. The isotherm and kinetic models which best displayed the outcome obtained were the Freundlich model and pseudo-second-order kinetic for TEX, respectively. In addition to the main aim of present study, GO-PS was regenerated for nine cycles and the reused adsorbent exhibited the adsorption ability equivalent to the original, approximately.